A process is the change a system undergoes from one equilibrium state to another. Processes often involve either mechanical work or heat transfer.

Examples

For example, transferring a heated ball of iron to water would be a process involving heat transfer to water.

Another example is a truck with combusted diesel exhaust cooling down to normal temperature and pressure.

  • Initial state: () – 2 independent, intensive properties as per the State Postulate
  • Final state: () – state is specified (could calculate or other properties)

This is an example of an isobaric process.

We can draw a state diagram like this:

Types of Processes

  • Isobaric – constant pressure,
  • Isothermal – constant temperature,
  • Isochoric – constant specific volume,
  • Adiabatic – no heat transfer

Work Done

Given a process path, the area under the curve is the work output.