A system will inherently go through intermediate non-equilibrium states during a process.

A quasi-equilibrium process is sufficiently slow, such that the system remains infinitesimally close to thermodynamic equilibrium throughout.

Examples

  • Nickel ball that is cooling in such a way that it has uniform temperature distribution.

  • Piston motion in a car engine is a slow process relative to air molecule motion, such that it can be considered a quasi-equilibrium process.